CQU7007 – VIBRATIONAL AND ELECTRONIC SPECTROSCOPY

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LEVEL: Master and Doctorate

CREDITS: 4

MAIN TOPICS:

GROUP THEORY AND MOLECULAR SYMMETRY APPLIED TO SPECTROSCOPIC STUDIES. INFRARED AND RAMAN (VIBRATIONAL) SPECTROSCOPY. Vibrational spectra in the IR and Raman: molecular origin of the phenomena of absorption and scattering of light, spectral patterns, instrumentation. Diatomic and polyatomic molecules. Analysis of vibrational modes and applications to inorganic compounds. ELECTRONIC SPECTROSCOPY. Electronic structure: polyelectronic atoms. Crystal and Ligand Field Theory. Molecular Orbital Theory applied to the interpretation of electronic spectra of coordination compounds. Energy level diagrams. Applications.

RECOMMENDED LITERATURE:

ENGEL, T. Quantum chemistry and spectroscopy. 3rd ed. London: Pearson, 2013.

LARKIN, P. Infrared and Raman Spectroscopy: principles and spectral interpretation. San Diego: Elsevier, 2011.

DE OLIVEIRA, G. M. Simetria de moléculas e cristais: fundamentos da espectroscopia vibracional. Porto Alegre: Bookman, 2009.

HARRIS, D. C.; BERTOLUCCI, M. D. Symmetry and spectroscopy: an introduction to vibrational and electronic spectroscopy. Mineola, NY: Dover, 1989.

COTTON, F. A. Chemical applications of group theory. 3rd ed. New York: Wiley-Interscience, 1990.

SALA, O. Fundamentos da espectroscopia Raman e no infravermelho. São Paulo: UNESP, 1996.

NAKAMOTO, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 6th ed. New York: John Wiley & Sons, 2009.

FERRARO, J. R.; BROWN, C. W.; NAKAMOTO, K. Introductory Raman spectroscopy. 2nd ed. London: Academic Press, 2002.

COLTHUP, N. B.; DALY, L. H.; WIBERLY, S. E. Introduction to Infrared and Raman Spectroscopy. 2nd ed. New York: Academic Press, 1975.

FIGGIS, B. N.; HITCHMAN, M. A. Ligand field theory & its applications. New York: Wiley-VCH, 2000.

LEVER, A. B. P. Inorganic electronic spectroscopy. 2nd ed. Amsterdam: Elsevier, 1984.

SOLOMON, E. I.; LEVER, A. B. P. (Eds.) Inorganic electronic structure and spectroscopy. New York: Wiley-Interscience, 2006. v. 1: Methodology.

SOLOMON, E. I.; LEVER, A. B. P. (Eds.) Inorganic electronic structure and spectroscopy. New York: Wiley-Interscience, 2006. v. 2: Applications and case studies.